Electrons and holes are injected into the organic layer at the electrodes and form excitons, a bound state of the electron and hole electrons and holes are both fermions with half integer spin. Highly efficient and stable phosphorescent organic light. Organic molecular solids 2007 isbn 9783527405404 heinzel, t. Highly efficient singlelayer phosphorescent organic light. Highly efficient oleds with phosphorescent materials hartmut yersin this brandnew monograph on organic light emitting diodes, edited by a pioneer, and written by frontline researchers from academia and industry, provides access to the latest findings in this rapidly growing field. Confining triplet excitons and carriers in phosphor.
More than ten contributions cover all areas from theory and basic principles, to different emitter materials and applications in production. Download citation in highly efficient oleds with phosphorescent materials this brandnew monograph on organic light emitting diodes, edited by a pioneer. The efficiency of oleds is currently one major research concern. High efficiency green phosphorescent oleds using doublehost.
Rgb phosphorescent organic lightemitting diodes by using. Highly efficient organic lightemitting diodes from. The essential resource that offers a comprehensive understanding of oled optimizations highly efficient oleds. Materials based on thermally activated delayed fluorescence tadf offers substantial information on the working principle of oleds and on new types of emitting materials organic and inorganic. Progress in smallmolecule luminescent materials for. In january 2008 sony announced the release of the first organic lightemitting diode oledbased television figure 1 into the u. Get your kindle here, or download a free kindle reading app. Request pdf highly efficient oleds with phosphorescent materials introductionissues of redemissive materialsredphosphorescent iridium complexes lowest excited state of iridium. One of the complexes, fbi2iracac fbi 29,9diethyl9hfluoren2yl1hbenzoimidazole, was also characterized by singlecrystal x. Cyclometallated organoiridium complexes as emitters in. Mingming hu,a yang liu,a yi chen,a wenxuan song,a lei gao,c haichuan mu,b jinhai huangd and jianhua sua two novel host materials, 3dibenzob,dfuran4yl94,6diphenyl1,3,5triazin2yl9hcarbazole. Sn formation in host tn formation in host sn formation in dopant. Chrysenebased electrontransporters realizing highly. A major barrier to widespread adoption at this point is the efficiency droop that occurs for oleds at practical brightness.
Pdf we demonstrate highly efficient white and nonwhite hybrid organic. Pdf nitrogen heterocyclecontaining materials for highly. A series of chrysenebased electrontransporters named bnpypcs n 2, 3, 4 endcapped with two 3,5dipyridinnylphenyl moieties with high thermal and electrical stability were successfully developed. Highly efficient oleds with phosphorescent materials by. Highly efficient oleds with phosphorescent materials yersin, hartmut on. One major challenge is to have a suitable blue fluorophore material to fully utilize. Design principles for highly efficient organic light. Highly phosphorescent biscyclometalated iridium complexes.
Materials free fulltext highly efficient singlelayer. Materials are the base of oled devices and receive great attention from. The solutionprocessed blue phosphorescent oleds achieved a high brightness of 16,537 cd m. Highly efficient triazinecarbazolebased host material. Additional material properties required for triplet harvesting are outlined. Materials, devices, fabrication, characterization, and.
Highly efficient inverted organic lightemitting diodes. Operation and engineering of organic lightemitting diode oled devices. Rational design and characterization of heteroleptic. Here, we disclose the synthesis of a new phosphorescent. Organic lightemitting diodes oleds show potential as the nextgeneration solidstate lighting technology. These compounds readily undergo cyclometalation with iridium trichloride, and biscyclometalated iridium complexes, bi2iracac bi cyclometalated benzoimidazole. Highly efficient phosphorescent materials based on. Download it once and read it on your kindle device, pc, phones or tablets. Pdf highly efficient fluorescentphosphorescent tripletharvesting. Goldiii complexes are emerging as promising phosphorescent emitters for high efficiency organic lightemitting diodes oleds. Cyclometallated complexes for oleds synthesis of cyclometallated ir complexes.
A highly efficient green phosphorescent organic lightemitting diode pholed was achieved from two coevaporated materials. Materials, devices and applications woodhead publishing series in electronic and optical materials book 36 kindle edition by buckley, alastair. Holeelectron recombination, aka exciton formation reineke, s baldo, m. Organometallic complexes as phosphorescent emitters in oleds. Lai, and chiming che 8 energytransfer processes between phosphorescent guest and fluorescent host molecules in phosphorescent oleds isao tanaka and shizuo tokito. Highly efficient oleds with phosphorescent materials. A series of spirofluorenebased host materials for efficient. Feng, yansong and zhuang, xuming and zhu, dongxia and liu, yu and wang, yue and bryce, martin r. Green inverted organic lightemitting diodes oleds based on a thermally activated delayed fluorescent tadf emitter, 2pheyl4carbazole9hthioxanthen9one10,10dioxide, with a cathode of indium tin oxide itozno injecting electrons efficiently into the electron transporting layer of alq3, are demonstrated for the first time. Along with phosphorescent material harnessing phosphorescence 7, 17, triplet triplet annihilation 18 were also used. A maximum external quantum efficiency eqe of over 15% was obtained for a phosphorescent ioled by. In this paper, we report on a highly efficient ioled with high storage stability in air. An effective thermally activated delayed fluorescence host material.
Request permissions highly efficient yellow phosphorescent oleds based on two novel bipolar host materials s. Their energy levels can be tuned by the change of heterocyclic cores and their nitrogen atom orientations, and decrease of singlet. Transfer processes between phosphorescent guest and. Highly efficient green phosphorescent organic lightemitting diodes based on tetraphenyl silicon derivative host materials. Also, a highly efficient phosphorescent ioled with a low driving voltage has never been realized. However, despite recent advances in the coordination and organometallic chemistry of gold, only few compounds have been successful in highperformance devices. Highly efficient oleds with phosphorescent materials pdf free. Spirofluorene molecular platforms were utilized to construct host materials for highly efficient green phosphorescent oleds. Luminescence properties of phosphorescent and fluorescent materials. Highly efficient yellow phosphorescent oleds based on two. Goldiii complexes are emerging as promising phosphorescent emitters for highefficiency organic lightemitting diodes oleds.
Highly efficient white oleds for lighting applications sven muranoa, markus burgharta, jan birnstock a. Read an excerpt table of contents pdf index pdf preface pdf chapter 01 pdf highly efficient oleds with phosphorescent materials. In this paper, two oled device concepts are introduced. Recent advancements of high efficient donoracceptor type blue. Highly efficient oleds with phosphorescent materials wiley. Edge technology development headquarters, canon inc. Here, we employed an efficient blue fluorophore pbippitpa with a high. Second, a path towards highly efficient, longlived deep blue systems is shown. Highly efficient green solution processable organic light. Highly efficient fluorescencephosphorescence hybrid white organic. Highly efficient yellow phosphorescent oleds based on two novel bipolar host materials. Phosphorescent iridium complexes akira tsuboyama leading. An exciton is formed by the coulombic attraction between. Advanced functional materials 2014, 24 21, 32683275.
Along with phosphorescent material harnessing phosphorescence 7, 17, triplettriplet annihilation 18 were also used. Highly efficient green phosphorescent organic light. Request pdf highly efficient oleds with phosphorescent materials introductionissues of redemissive materialsred phosphorescent iridium complexes lowest excited state of iridium. In highly efficient oleds with phosphorescent materials. Like all types of oled, phosphorescent oleds emit light due to the electroluminescence of an organic semiconductor layer in an electric current.
Nitrogen heterocyclecontaining materials for highly efficient phosphorescent oleds with low operating voltage article pdf available october 2014 with 777 reads how we measure reads. Highly efficient oleds have recently been realized without the use of heavy atoms by employing a tadf material as emitter 45 and it has also been found that the amount of the phosphorescent. Highly efficient oleds with phosphorescent materials wiley online. Use features like bookmarks, note taking and highlighting while reading organic lightemitting diodes oleds. Pyridinecontaining electrontransport materials for highly efficient blue phosphorescent oleds with ultralow operating voltage and reduced efficiency rolloff. Pyridinecontaining bipolar host materials for highly. Highly efficient skyblue phosphorescent oleds were obtained when employing tpsif as the host and iridiumiii bis4,6difluorophenylpyridinaton,c 2. New generation of high efficient oled using thermally activated. Highly efficient oleds with phosphorescent materials pdf.
Observation of thermal equilibrium of triplet excited states conclusion. Highly efficient skyblue phosphorescent oleds were obtained when employing tpsif as the host and iridiumiii bis4,6difluorophenylpyridinaton,c29firpic as the guest. We highlight recent progress in highly efficient oleds at high brightness, where improvements are made by. The electropumped organic molecular film can be made by highly efficient lightemitting devices, as discovered by tang and van slyke for small molecules and by burroughes et al. Phosphorescent organic lightemitting diode wikipedia.
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